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Sediments reveal the ancient ocean during a mass extinction event

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Sediments reveal the ancient ocean during a mass extinction event


Sediments reveal the ancient ocean during a mass extinction event
A quarry illustrating bands of stratified limestone from the ancient seafloor in what is now Mercato San Severino in Italy. Credit: F. Tissot

About 183 million years ago, volcanic activity in modern South Africa unleashed an estimated 20,500 gigatons of carbon dioxide (CO2) into the ocean–atmosphere system over a period of 300 to 500 thousand years. Known as the Toarcian Oceanic Anoxic Event (T-OAE), the lack of oxygen, or anoxia, in the water during this time caused a mass extinction of marine species.

Human activity since the industrial revolution has already resulted in cumulative CO2 emissions representing 12% of the total CO2 released during the entire T-OAE, in less than 0.1% of the time. The T-OAE foreshadows what might happen to our oceans if greenhouse gas emissions continue to increase.

“You can see lots of fossils within ocean sediments before the T-OAE, and then suddenly they disappear,” says Caltech’s Francois Tissot, Professor of Geochemistry and Heritage Medical Research Institute Investigator.

Tissot is a co-author on a new study that was published on June 24 in the Proceedings of the National Academy of Sciences, describing the extent of the ocean anoxia during the T-OAE.

Led by researchers from George Mason University, the team collected 30 samples of stratified limestone from the Mercato San Severino region in southern Italy to assess the severity of ocean deoxygenation during the T-OAE.

The team analyzed the samples for their uranium content and isotopic composition. Isotopes are twin version of an element with different number of neutrons, and thus very slightly different masses.

The relative abundance of isotopes of uranium in the ocean depends on the amount of anoxia. This means that by measuring the isotopic composition of uranium in the ocean, scientists can infer the amount of anoxia in the ocean.

In the absence of actual seawater samples from the past, scientists are able to use a proxy for it, such as carbonate rocks, which faithfully record the seawater composition.

When there is plenty of oxygen in the ocean, uranium likes to stay in its soluble form, dissolved in the seawater. But when oxygen in the water becomes more scarce, then uranium begins to precipitate out of the seawater, and settles into sediments on the ocean floor.

Thus, through careful modeling developed by former Caltech postdoctoral scholar Michael Kipp, Tissot, and collaborators, the amount of uranium in seafloor samples can indicate the percentage of oxygen in the ocean at the time of the T-OAE.

“Using this model, we found that anoxia peaked at 28 to 38 times of the modern ocean,” says Tissot. “Today, only about 0.2% of the ocean floor is covered with anoxic sediments, similar to those found in the Black Sea. At the time of the T-OAE, 183 million years ago, it was 6% to 8% of the ocean floor that was covered in anoxic sediment.”

The results indicate that past OAE events can foreshadow the effects of anthropogenic CO2 emissions on marine ecosystems.

“If we don’t curb carbon emissions and continue on an increasing CO2 trajectory, we can clearly see that there will be severe negative impacts on the ocean’s ecosystem,” says Tissot.

The paper is titled “Carbonate uranium isotopes record global expansion of marine anoxia during the Toarcian Oceanic Anoxic Event.”

More information:
Mariano N. RemĂ­rez et al, Carbonate uranium isotopes record global expansion of marine anoxia during the Toarcian Oceanic Anoxic Event, Proceedings of the National Academy of Sciences (2024). DOI: 10.1073/pnas.2406032121

Citation:
Sediments reveal the ancient ocean during a mass extinction event (2024, June 25)
retrieved 25 June 2024
from https://phys.org/news/2024-06-sediments-reveal-ancient-ocean-mass.html

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part may be reproduced without the written permission. The content is provided for information purposes only.





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Australia’s giant lizards help save sheep from being eaten alive

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Australia’s giant lizards help save sheep from being eaten alive


Australia's giant lizards help save sheep from being eaten alive
Jameson compared the scavenging activity of different animals by leaving dead rats at feeding stations, with camera traps, across the landscape. Credit: Tom Jameson

Giant lizards called heath goannas could save Australian sheep farmers millions of dollars a year by keeping blowfly numbers down—and must be prioritized in conservation schemes to boost native wildlife, say researchers.

A study led by the University of Cambridge has found that heath goannas—a species of giant, scavenging lizard—act as natural cleanup crews by clearing maggot-ridden animal carcasses from the landscape.

This reduces the emergence of blowflies, which attack sheep by laying eggs on their backsides that hatch into flesh-eating maggots. The disease, known as “fly strike,” costs the Australian sheep farming industry an estimated $280 million a year.

This study was carried out at 18 sites across the Marna Banggara Rewilding Project area on Australia’s southern Yorke Peninsula, where over 90% of the native mammals are now extinct. The work is published in the journal Ecology and Evolution.







The heath goanna is an endangered species of giant lizard native to the heathlands of southern Australia that can grow up to a meter and a half in length. It feeds on the dead carcasses of other animals, as well as catching live animals. Credit: Tom Jameson

The study found that heath goannas perform a superior blowfly control service to introduced European mammals, including red foxes and cats, which are displacing them.

The researchers say that boosting populations of native large reptiles like heath goannas is vital in restoring Australia’s ecosystem and the services it supports.

“We found that Australia’s native scavengers like heath goannas are much more effective in removing blowflies from the landscape than invasive scavengers like European foxes and cats,” said Tom Jameson, a Ph.D. researcher in the University of Cambridge’s Department of Zoology and first author of the report.

Australia's giant lizards help save sheep from being eaten alive
Camera trap footage revealed which scavenging animal had found the dead rat, and how quickly. Eighteenth century European settlers to Australia brought with them red foxes for hunting, and cats as pets. Australia’s native wildlife has since been decimated by them. Credit: Tom Jameson

High densities of blow flies put sheep at risk of fly strike, a disease where blowfly maggots burrow into the sheep’s flesh and start to eat it alive, causing painful wounds. This affects the market value of the sheep, reduces breeding success and often results in death.

“Blowflies are a massive problem for the Australian sheep farming industry. They cause a horrible disease that is expensive for farmers to manage and a real animal welfare problem for sheep,” said Jameson.

This is the first study to show the importance of large reptiles as scavengers.







Reptiles like the heath goanna act as natural clean-up crews by clearing maggot-ridden animal carcasses from the landscape. Researchers say that boosting populations of native large reptiles like heath goannas is vital in restoring Australia’s ecosystem and the services it supports. Credit: Tom Jameson

To get these results, Jameson compared the scavenging activity of different animals in a region of southern Australia. He left hundreds of dead rats at feeding stations, with camera traps, across the landscape. He returned after five days to see whether the rats had been eaten, and to count the number of blowfly maggots left on any remaining carcasses. Camera trap footage revealed which scavenging animal had found the rat, and how quickly.

Native Australian scavengers ate more of the dead rats, and with them the flesh-eating maggots, than scavengers introduced from Europe.

Australia's giant lizards help save sheep from being eaten alive
Reptiles like the heath goanna are the largest remaining native land scavengers in much of Australia today. Native Australian scavengers were seen to eat more of the dead rats, and with them the flesh-eating maggots, than scavengers introduced from Europe. Credit: Tom Jameson

“It was disgusting—we were counting maggots. After five days, we’d find over 1,000 maggots in one rat if a scavenger hadn’t found it. Those maggots produce blowflies that can spread up to 20 kilometers in a week, putting local sheep flocks at risk of fly strike,” said Jameson.

In natural situations, any dead animal in the landscape will fill with blowfly maggots very quickly.

“The results suggest that conservation work in southern Australia to remove invasive species should also focus on boosting the population of heath goannas and other native species because they’re really important for the wider ecosystem,” said Jameson. “As well as benefiting native wildlife, this will have knock-on benefits for local agricultural industry, and also attract more wildlife tourism.”

  • Australia's giant lizards help save sheep from being eaten alive
    The study was carried out at the Marna Banggara Rewilding Project area on Australia’s southern Yorke Peninsula, where over 90% of the native mammals are now extinct. Credit: Tom Jameson
  • Australia's giant lizards help save sheep from being eaten alive
    Jameson spent a total of six months living remotely in Australia, mostly alone, to conduct the research. He says it was “an absolute privilege to work in this utterly stunning landscape with such wonderful wildlife.” Credit: Tom Jameson

Marna Banggara, supported by Narungga traditional owners, is an ambitious rewilding project that aims to restore ecosystem health in the region by reintroducing missing native Australian species.

Eighteenth-century European settlers to Australia brought with them red foxes for hunting, and cats as pets. Australia’s native wildlife—including many scavengers—has since been decimated by them.

The heath goanna is an endangered species of giant lizard native to the heathlands of southern Australia that can grow up to a meter and a half in length. It feeds on the dead carcasses of other animals, as well as catching live animals.

Reptiles like the heath goanna are the largest remaining native land scavengers in much of Australia today.

More information:
Squamate Scavenging Services: Heath goannas (Varanus rosenbergi) support carcass removal and may suppress agriculturally damaging blowflies, Ecology and Evolution (2024).

Citation:
Australia’s giant lizards help save sheep from being eaten alive (2024, June 25)
retrieved 25 June 2024
from https://phys.org/news/2024-06-australia-giant-lizards-sheep-eaten.html

This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no
part may be reproduced without the written permission. The content is provided for information purposes only.





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Scientists design novel wirelessly powered relay transceiver array

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Scientists design novel wirelessly powered relay transceiver array


Towards wider 5G network coverage: novel wirelessly powered relay transceiver
The proposed transceiver design enables high power conversion efficiency and conversion gain, enhancing 5G network coverage even in areas with link blockage. Credit: 2024 IEEE MTT-S International Microwave Symposium

A novel 256-element wirelessly powered transceiver array for non-line-of-sight 5G communication, featuring efficient wireless power transmission and high-power conversion efficiency, has been designed by scientists at Tokyo Tech.

The innovative design can enhance the 5G network coverage even to places with link blockage, improving flexibility and coverage area, and potentially making high-speed, low-latency communication more accessible.

Millimeter wave 5G communication, which uses extremely high-frequency radio signals (24 to 100 GHz), is a promising technology for next-generation wireless communication, exhibiting high speed, low latency, and large network capacity.

However, current 5G networks face two key challenges. The first one is the low signal-to-noise ratio (SNR). A high SNR is crucial for good communication. Another challenge is link blockage, which refers to the disruption in signal between transmitter and receiver due to obstacles such as buildings.

Beamforming is a key technique for long-distance communication using millimeter waves which improves SNR. This technique uses an array of sensors to focus radio signals into a narrow beam in a specific direction, akin to focusing a flashlight beam on a single point. However, it is limited to line-of-sight communication, where transmitters and receivers must be in a straight line, and the received signal can become degraded due to obstacles.

Furthermore, concrete and modern glass materials can cause high propagation losses. Hence, there is an urgent need for a non-line-of-sight (NLoS) relay system to extend the 5G network coverage, especially indoors.

To address these issues, a team of researchers led by Associate Professor Atsushi Shirane from the Laboratory for Future Interdisciplinary Research of Science and Technology at Tokyo Institute of Technology(Tokyo Tech) designed a novel wirelessly powered relay transceiver for 28 GHz millimeter-wave 5G communication. Their paper is published in the journal IEEE Microwave and Wireless Technology Letters.

Towards wider 5G network coverage: novel wirelessly powered relay transceiver
The board includes gallium arsenide diodes, balun ICs, DPDT switch ICs, and digital ICs. This circuit generates DC from 24GHz WPT signal and downconverts 28GHz RF signal to 4GHz IF signal simultaneously. Credit: 2024 IEEE MTT-S International Microwave Symposium

Explaining the motivation behind their study, Shirane says, “Previously, for NLoS communication, two types of 5G relays have been explored: an active type and a wireless-powered type. While the active relay can maintain a good SNR even with few rectifier arrays, it has high power consumption.

“The wirelessly powered type does not require a dedicated power supply but needs many rectifier arrays to maintain SNR due to low conversion gain and uses CMOS diodes with lower than ten percent power conversion efficiency. Our design addresses their issues while using commercially available semiconductor integrated circuits (ICs).”

The proposed transceiver consists of 256 rectifier arrays with 24 GHz wireless power transfer (WPT). These arrays consist of discrete ICs, including gallium arsenide diodes, and baluns, which interface between balanced and unbalanced (bal–un) signal lines, DPDT switches, and digital ICs.

Notably, the transceiver is capable of simultaneous data and power transmission, converting 24 GHz WPT signal to direct current (DC) and facilitating 28 GHz bi-directional transmission and reception at the same time.

The 24 GHz signal is received at each rectifier individually, while the 28 GHz signal is transmitted and received using beamforming. Both signals can be received from the same or different directions and the 28 GHz signal can be transmitted either with retro-reflecting with the 24 GHz pilot signal or in any direction.

Testing revealed that the proposed transceiver can achieve a power conversion efficiency of 54% and a conversion gain of –19 decibels, higher than conventional transceivers while maintaining SNR over long distances. Additionally, it achieves about 56 milliwatts of power generation which can be increased even further by increasing the number of arrays. This can also improve the resolution of the transmission and reception beams.

“The proposed transceiver can contribute to the deployment of the millimeter-wave 5G network even to places where the link is blocked, improving installation flexibility and coverage area,” said Shirane.

More information:
Michihiro Ide et al, A 256-Element Phased-Array Relay Transceiver for 5G Network Using 24-GHz Wireless Power Transfer With Discrete ICs, IEEE Microwave and Wireless Technology Letters (2024). DOI: 10.1109/LMWT.2024.3395300

Citation:
Towards wider 5G network coverage: Scientists design novel wirelessly powered relay transceiver array (2024, June 17)
retrieved 25 June 2024
from https://techxplore.com/news/2024-06-wider-5g-network-coverage-scientists.html

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part may be reproduced without the written permission. The content is provided for information purposes only.





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New yttrium-doping strategy enhances 2D transistors

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New yttrium-doping strategy enhances 2D transistors


An yttrium-doping technique to metallize molybdenum disulfide
Theoretical illustration of Yttrium doping-induced 2D metallization ohmic contact technology. Credit: Nature Electronics (2024). DOI: 10.1038/s41928-024-01176-2

Electronics engineers and materials scientists have been trying to identify materials that could help to boost the performance of electronics further, overcoming the inherent limitations of silicon-based transistors. Two-dimensional (2D) semiconductors have advantageous properties that make them promising candidates for the development of better performing transistors.

Most notably, 2D semiconductors are atomically thick and exhibit high carrier mobilities, two qualities that could improve the electrostatic control and ON-state performances of short-channel field-effect transistors (FETs). Despite their advantages, these materials exhibit high contact resistances linked to so-called Fermi-level-pinning effects, which significantly reduce their performance in transistors.

Researchers at Peking University and Chinese Academy of Sciences recently introduced a new yttrium-doping strategy that could help to overcome this key limitation of 2D semiconductors, facilitating their effective integration in electronics.

This strategy, outlined in a paper published in Nature Electronics, can convert semiconducting molybdenum disulfide (MoS2) into metallic MoS2, improving band alignment and facilitating the use of MoS2 for fabricating ohmic contacts for 2D transistors.

“We placed a semi-metal layer between a metal electrode and a two-dimensional semiconductor,” Chenguang Qiu, co-author of the paper, told Tech Xplore. “This semi-metal layer enhances the efficiency of carrier injection from the metal electrode to the two-dimensional semiconductor. This idea is inspired by the traditional silicide structure in silicon-based transistors.”

The key goal of the recent study by Qiu and his colleagues was to address the issue of Fermi-level pinning effects at the interface between metal and 2D semiconductor layers in 2D transistors. This is a critical bottleneck in the development of 2D electronics, which has so far prevented their future large-scale fabrication.

“We have developed the plasma-deposition-annealing (PDA) method to achieve yttrium doping in the surface layer of MoS2,” Qiu said. “First, the patterned local contact areas were treated with low-power soft plasma to generate active sites. Next, a Y/Ti/Au stacked metal was deposited, and the 1 nm-thick active metal Y was used as a solid-state doping source.”

An yttrium-doping technique to metallize molybdenum disulfide
Fabrication and characterization of two-dimensional metallization. Credit: Nature Electronics (2024). DOI: 10.1038/s41928-024-01176-2

The Y atoms used to dope MoS2 diffuse into the active sites generated using low-power plasma. The researchers then activated them in the top layer of the material, using high-temperature annealing in an inert gas environment.

“Due to the preparation of hyperfine patterned structures, great thermal stability after annealing, and the all-solid-state nature, this PDA doping process is compatible with advanced-node wafer-scale integration,” Qiu said.

In their paper, the researchers introduced a new concept, which they refer to as “rare earth element yttrium doping-induced 2D phase transition.” This phase transition is essentially the metallization that they observed when they applied their yttrium doping strategy to MoS2.

“We have invented a selective-area single-atomic-layer surface doping technique,” Qiu said. “This breakthrough overcomes the traditional engineering limitation where the junction depth of ion implantation doping cannot be less than 5 nanometers, achieving for the first time a doping depth pushed to the atomic layer limit of 0.5 nanometers.”

Using their yttrium-doping strategy, Qiu and his colleagues developed ultra-short MoS2-based channel ballistic transistors that performed well as ohmic contacts and had great switching capabilities. In the future, these transistors could contribute to the development of new sub-1 nanometer node chips that can attain remarkable performances while consuming less power than conventional chips.

“We now hope to develop equally excellent p-type ohmic contacts suitable for 2D semiconductors,” Qiu added. “This would enable the fabrication of complementary symmetrical CMOS transistors, which can be used to build higher performance and lower power consumption large-scale integrated circuits.”

More information:
Jianfeng Jiang et al, Yttrium-doping-induced metallization of molybdenum disulfide for ohmic contacts in two-dimensional transistors, Nature Electronics (2024). DOI: 10.1038/s41928-024-01176-2

© 2024 Science X Network

Citation:
New yttrium-doping strategy enhances 2D transistors (2024, June 25)
retrieved 25 June 2024
from https://techxplore.com/news/2024-06-yttrium-doping-strategy-2d-transistors.html

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US regulator says TikTok may be violating child privacy law

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US regulator says TikTok may be violating child privacy law


tiktok
Credit: Unsplash/CC0 Public Domain

The US Federal Trade Commission (FTC) announced Tuesday that it had referred a complaint against TikTok to the Justice Department, saying the popular video sharing app may be violating child privacy laws.

The complaint, which also names TikTok’s Chinese parent company Bytedance, stems from an investigation launched following a 2019 settlement, the FTC said in a statement.

At the time, the US regulator accused TikTok’s predecessor, Musical.ly, of having improperly collected child users’ personal data.

TikTok agreed to pay $5.7 million under the settlement and to take actions to come into compliance with the Children’s Online Privacy Protection Act (COPPA), a 1998 law.

FTC chair Lina Khan said Tuesday on X that the follow-up investigation had “found reason to believe that TikTok is violating or about to violate” COPPA and other federal laws.

A separate FTC statement said that the public announcement of the referral was atypical, but “we have determined that doing so here is in the public interest.”

Neither Khan nor the FTC statement further specified the violations TikTok and Bytedance were believed to have committed.

TikTok said Tuesday on X that it had worked for more than a year with the FTC “to address its concerns,” and was “disappointed” the agency was “pursuing litigation instead of continuing to work with us on a reasonable solution.”

“We strongly disagree with the FTC’s allegations, many of which relate to past events and practices that are factually inaccurate or have been addressed,” it said.

“We’re proud of and remain deeply committed to the work we’ve done to protect children and we will continue to update and improve our product.”

The complaint comes a day after US Surgeon General Vivek Murthy called for new restrictions on social media to combat a sweeping mental health crisis among young people.

Among the steps proposed by Murthy in his New York Times op-ed was notably a tobacco-style warning label “stating that social media is associated with significant mental health harms for adolescents.”

TikTok, with roughly 170 million US users, is facing a possible ban across the United States within months, as part of legislation signed by President Joe Biden in late April.

The company has filed a lawsuit challenging the constitutionality of the ban, which is working its way through US courts.

Meanwhile TikTok has been targeted by several civil suits alleging the company insufficiently protected minors who use the platform.

© 2024 AFP

Citation:
US regulator says TikTok may be violating child privacy law (2024, June 19)
retrieved 25 June 2024
from https://techxplore.com/news/2024-06-tiktok-violating-child-privacy-law.html

This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no
part may be reproduced without the written permission. The content is provided for information purposes only.





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